Metalltrifluorphosphin-Komplexe, XXX / Metal-Trifluorophosphine Complexes, XXX
Open Access
- 1 March 1972
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 27 (3) , 302-304
- https://doi.org/10.1515/znb-1972-0315
Abstract
The title compound, CpMn (PF3) 3, is formed by photochemically induced CO/PF3 exchange with CpMn (CO)3 in a THF-solution. The yellow crystalline solid is obtained in 70% yield. It is obvious that in the course of this reaction intermediate THF-substitution-products are formed. For the first time we were able to prove that besides CpMn (CO) 2THF, CpMn (THF) 2CO is also a product of the above reaction. These intermediate THF-complexes are already at normal pressure able to exchange THF for PF3.Keywords
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