Uranium(IV)-crown-ether complexes and cryptates. 1H Nuclear magnetic resonance study, and X-ray crystal and molecular structure of tetrachloro-(2,5,8,15,18,21-hexaoxatricyclo[20.4.0.09,14]hexacosane)uranium(IV)
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 90-92
- https://doi.org/10.1039/c39780000090
Abstract
1 H N.m.r. evidence for direct co-ordination of uranium to the oxygen atoms in a new UCl4-dicyclohexyl-18-crown-6 complex is confirmed by an X-ray structural determination; several uranium(IV) salt–crown-ether complexes and cryptates also exhibiting very large n.m.r. shifts are reported.Keywords
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