A Convenient Method for the Synthesis of Substituted 2-Methoxycarbonyl- and 2-Cyano-allylphosphonates. The Allyl Phosphite - Allylphosphonate Rearrangement
- 1 January 1990
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1990 (09) , 799-801
- https://doi.org/10.1055/s-1990-27019
Abstract
The thermally induced Arbuzov rearrangement of allyl diethyl phosphites gives, under unprecedented mild conditions, a variety of diethyl allylphosphonates with high stereoselectivity and in high yield.Keywords
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