A diepoxide cyclization cascade initiated through the action of pig liver esterase
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 351-352
- https://doi.org/10.1039/c39870000351
Abstract
An enantiomerically pure, functionalised diepoxide is converted, upon treatment with pig liver esterase under buffered aqueous conditions, into a cyclized product via a stepwise, stereospecific diepoxide cyclization; the crystal structure of the bis-lactone (5) has been determined.Keywords
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