Compounds with molecular asymmetry due solely to a tercovalent non-bridgehead nitrogen atom: optically active N-chloro-2,2-diphenylaziridine
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1133-1134
- https://doi.org/10.1039/c39720001133
Abstract
Optically active N-chloro-2,2-diphenylaziridine, whose asymmetry is due solely to the chiral nitrogen atom, has been obtained by asymmetric chlorination of 2,2-diphenylaziridine by (1R:2R)-(–)-isobornyl hypochlorite and (S)-(+)-(N-chloro)methylphenylsulphoximide.Keywords
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