Anion dependence of Ag(i) reactions with 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (bptz): isolation of the molecular propeller compound [Ag2(bptz)3][AsF6]2
- 19 November 2004
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 1,p. 46-47
- https://doi.org/10.1039/b410811f
Abstract
The new compound [Ag2(bptz)3][AsF6]2, prepared from the reaction of bptz with Ag[AsF6] in CH3CN, is stable in solution as well as the solid-state and exhibits an unprecedented propeller arrangement of three bptz ligands spanning two Ag(I) ions with [AsF6]− anions located in the folds of the cation.Keywords
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