Toward constructing nanoscale hydroxo–lanthanide clusters: syntheses and characterizations of novel tetradecanuclear hydroxo–lanthanide clusters
- 29 January 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 4,p. 368-369
- https://doi.org/10.1039/b105969f
Abstract
Two novel tetradecanuclear hydroxo–lanthanide complexes, formulated as Ln14(μ4-OH)2(μ3-OH)16(μ-η2-acac)8(η2-acac)16, Ln = Tb, 1; Eu, 2; acac = acetylacetonato, were synthesized and characterized by single-crystal X-ray diffraction, elemental analysis and phosphorescence spectroscopy.Keywords
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