The formation of alkoxysilanes from the interaction of linear and cyclic thiosilanes and disilthianes with oxygen heterocyclic rings

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Abstract
Ethylene oxide, propene oxide, cyclohexene oxide, trimethylene oxide, and tetrahydrofuran react with a variety of linear and cyclic silicon–sulphur compounds to produce a range of monomeric and polymeric alkoxysilanes. β-Propiolactone undergoes alkyl–oxygen fission to insert into silicon–sulphur bonds.