The first practical approach to optically pure cyclopropanes derived from trans γ-hydroxy enones
- 11 April 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 9,p. 1323-1325
- https://doi.org/10.1039/b001973i
Abstract
A new approach for the synthesis of optically pure cyclopropanes from trans γ-hydroxy enones and stabilised phosphorus ylides is presented; the use of light and a triplet sensitiser leads to a dramatic increase in reaction rate and isolated yield.Keywords
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