Transition-metal chemistry of hexafluorobutadiene. Facile hydrolysis of (hexafluoro-1-metalla-3-cyclopentene)rhodium complexes to give tetrafluoro-1-metalla-3-cyclopenten-2-one and tetrafluoro-1-metalla-2-cyclopenten-4-one complexes. Crystal and molecular structures of trans-[cyclo][(RhCF2CF:CFCO)Cl(PPh3)2], mer-[cyclo][(RhCF2CF:CFCF2)Cl(PMe3)3], and mer-[cyclo][(RhCF:CFCOCF2)Cl(PMe3)3]
- 1 August 1993
- journal article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 12 (8) , 3109-3117
- https://doi.org/10.1021/om00032a038
Abstract
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