Hydrophosphination of alkoxyalkenes catalyzed by transition metal complexes
- 1 January 2006
- journal article
- Published by Pleiades Publishing Ltd in Russian Journal of Organic Chemistry
- Vol. 42 (1) , 17-22
- https://doi.org/10.1134/s1070428006010039
Abstract
Diphenylphosphine adds to alkyl vinyl ethers in the presence of Ni(II) and Pd(II) complexes with a high regioselectivity, leading to exclusive formation of the corresponding Markownikoff adducts which were isolated as 1-alkoxyalkyl(diphenyl)phosphine oxides via oxidation with hydrogen peroxide.Keywords
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