Stereochemistry of intramolecular homolytic substitution at the sulphur atom of a chiral sulphoxide
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 189-190
- https://doi.org/10.1039/c39860000189
Abstract
The formation of the cyclic sulphoxide (R)-(6) by treatment of the bromoarene (R)-(2) with tributylstannane indicates that intramolecular homolytic substitution at the sulphur centre of the sulphoxide group proceeds with strict inversion of configuration.Keywords
This publication has 0 references indexed in Scilit: