Reaction of CN radicals with CH4 and O2
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 84 (1) , 9-15
- https://doi.org/10.1039/f29888400009
Abstract
A flash-photolysis laser-induced fluorescence technique has been used to study CN radical kinetics at 300 K. A radiative lifetime of 66.70 ± 4.60 ns has been measured for the B2Σ+ state of this radical. Rate constants for the reaction of the CN radical with CH4 and O2 have been measured to be (1.14 ± 0.06)× 10–12 and (18.2 ± 1.2)×10–12 cm3 molecule–1s–1, respectively.Keywords
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