Oxidation of tetraphenylborate by hexachloroiridate(IV)
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 20,p. 1238-1239
- https://doi.org/10.1039/c29710001238
Abstract
The reaction, BPh4 –+ 2IrCl6 2–+ H2O → Ph2BOH + Ph2+ 2IrCl6 3–+ H+, has been shown to occur quantitatively in aqueous solution; the kinetics are interpreted in terms of a mechanism involving BPh4˙ radicals which are also proposed as intermediates in certain electrochemical and photochemical reactions of BPh4 –.Keywords
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