Librational motion in sodium and lithium aluminium hydrides, studied by inelastic neutron scattering
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 69, 783-790
- https://doi.org/10.1039/f29736900783
Abstract
This paper gives an account of the observation of torsional modes of motion of the AlH– 4 ion in LiAlH4 and NaAlH4 and discusses these in relation to models for barriers to rotation. These barriers appear to be higher than those observed in other systems. The first observation in an energy-loss neutron spectrum of a M—H stretching frequency is reported.Keywords
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