A divergent route to nojirimycin analogues from L-serinal and 2-acetylthiazole
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 854-856
- https://doi.org/10.1039/c39900000854
Abstract
A five-step synthesis of O,N-protected (+)-3-deoxynojirimycin (7a) and (+)-3-deoxymannojirimycin (7b) from N-Boc L-serinal acetonide (1) employing 2-acetylthiazole (2) as a masked α-hydroxypropanal β-anion synthon is described.Keywords
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