Synthesis and X-ray crystal structure of the dimeric compound [C16H16N2O2Ti(BH3)2]2, a dimer of NN′-ethylenebis(salicylidenaminato)titanium containing seven-co-ordinate titanium(IV) and amino-borane as donor groups
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 300-301
- https://doi.org/10.1039/c39760000300
Abstract
The reaction of dichloro-NN′-ethylenebis(salicylidenaminato)titanium(IV), [Ti(salen)Cl2], with lithium tetrahydroborate gave, via addition of BH4 – to the imino-functions of the ligand, a dimeric seven-co-ordinate titanium(IV) compound containing amine-boranes as donor groups; its crystal and molecular structure together with spectroscopic data are reported.Keywords
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