Structure and chemistry of a zwitterionic amine–aldehyde adduct
- 21 August 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 18,p. 2106-2107
- https://doi.org/10.1039/b206639d
Abstract
The zwitterionic tetrahedral addition product 1 is the preferred form of the amino-aldehyde 4 in polar solvents and in the crystal, where a molecule of water controls the structure.Keywords
This publication has 8 references indexed in Scilit:
- Synthesis, structure and reactions of the most twisted amideJournal of the Chemical Society, Perkin Transactions 2, 2001
- New Chiral Auxiliaries for Enolate AlkylationsAngewandte Chemie International Edition in English, 1990
- The Anomeric Effect and Related Stereoelectronic Effects at OxygenPublished by Springer Nature ,1983
- Intramolecular nucleophilic attack of the tertiary amine group on the carbonyl group in 3,3-dimethyl-4-dimethylaminobutanalJournal of the Chemical Society, Chemical Communications, 1983
- Zwitterionic adducts between a strongly electrophilic ketone and tertiary aminesJournal of the American Chemical Society, 1980
- Geometrical reaction coordinates. II. Nucleophilic addition to a carbonyl groupJournal of the American Chemical Society, 1973
- Photoreduction by aminesChemical Reviews, 1973
- Rate and equilibrium constants for each step in the reaction of trimethylammonium ions with formaldehyde to give formocholine cations in aqueous solutionJournal of the American Chemical Society, 1970