Universal density-force relations for polymers near a repulsive wall
- 1 March 1997
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review E
- Vol. 55 (3) , 3116-3123
- https://doi.org/10.1103/physreve.55.3116
Abstract
The relation between the force exerted by long flexible polymer chains on a repulsive wall and the corresponding monomer density close to the wall is shown to imply a universal amplitude ratio. This is calculated in an ɛ expansion, and its importance in various situations is pointed out. These include a single polymer trapped between two parallel walls and a solution of polymers inducing a depletion interaction between the wall and a mesoscopic particle. Dilute and semidilute solutions in the half space are also considered.Keywords
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