Röntgenphotoelektronenspektroskopische Untersuchungen an einigen planaren Pseudohalogeno-d8-Übergangsmetallkomplexen / X-ray Photoelectron Spectra of Some Planar Pseudohalogeno-d8-Transition Metal Complexes
Open Access
- 1 August 1972
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 27 (8) , 884-887
- https://doi.org/10.1515/znb-1972-0803
Abstract
X-ray photoelectron spectra, pseudohalide complexes of gold (III), linkage isomerism Core binding energies of metals in the isomeric (Ph3As) 2Pd (NCS) 2 and (Ph3As) 2Pd (SCN) 2, and in [AsPh4] [AuX4] (X = CN-, tetrazolate, Cl-, N3 -) are reported. S- and N-Bonding mode can be distinguished in accord with semiemperical MO-calculations. XPS-results are correlated with Mößbauer spectra and the metal-cyanide and metal-tetrazolate bonds are discussed.Keywords
This publication has 0 references indexed in Scilit: