Vibrational effects on electron resonance spectra
- 1 January 1966
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 10 (4) , 339-347
- https://doi.org/10.1080/00268976600100461
Abstract
The temperature and isotope effects which have been observed in the electron resonance spectrum of the methyl radical are quantitatively correlated by attributing both to the out-of-plane vibration. An attempt is made to explain the temperature dependence of the benzene anion spectrum in terms of the same effect. The attempt fails, but some predictions are made.Keywords
This publication has 14 references indexed in Scilit:
- Temperature Dependence of the Hyperfine Splitting of the Methyl RadicalThe Journal of Chemical Physics, 1965
- On Variations in the Hyperfine Splitting of Benzene Negative Ion and on the Value of QJournal of the American Chemical Society, 1964
- Electron Spin Resonance Studies of Transient Alkyl RadicalsThe Journal of Chemical Physics, 1963
- The hyperfine coupling in cyclohexadienylMolecular Physics, 1963
- The electron spin resonance spectrum of CH3ĊHCOOH at 77°K inl-α-alanineMolecular Physics, 1961
- The Bakerian Lecture, The spectra and structures of free methyl and free methyleneProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1961
- Nuclear Hyperfine Interactions in Orbitally Degenerate States of Aromatic IonsThe Journal of Chemical Physics, 1961
- Indirect Hyperfine Interactions in the Paramagnetic Resonance Spectra of Aromatic Free RadicalsThe Journal of Chemical Physics, 1956
- Proton Hyperfine Interactions in Paramagnetic Resonance of Semiquinones1Journal of the American Chemical Society, 1955
- Hyperfine Splittings in the Paramagnetic Resonances of Free RadicalsThe Journal of Chemical Physics, 1953