Isolation of (+)-fusicocca-2,10(14)-diene, a 5-8-5 tricyclic diterpene hydrocarbon biosynthetically related to the fusicoccin aglycon from Fusicoccum amygdali and confirmation of its structure by total synthesis
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 16,p. 2473-2474
- https://doi.org/10.1039/a805033c
Abstract
(+)-Fusicocca-2,10(14)-diene, a double bond isomer of the putative fusicoccin biosynthetic intermediate, i.e., fusicocca-1,10(14)-diene, was isolated for the first time as a main hydrocarbon constituent from the fusicoccin-producing fungus Fusicoccum amygdali, and its stereostructure including absolute configuration was unambiguously confirmed by total synthesis.Keywords
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