The Structure of Hexamethyltungsten, W(CH3)6: Distorted Trigonal Prismatic with C3 Symmetry
- 1 January 1996
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 118 (12) , 3018-3024
- https://doi.org/10.1021/ja952231p
Abstract
No abstract availableThis publication has 39 references indexed in Scilit:
- A Monomeric Solvent-Free Bent Lanthanide Dialkyl and a Lanthanide Analog of a Grignard Reagent. Crystal Structures of Yb{C(SiMe3)3}2 and [Yb{C(SiMe3)3}I.cntdot.OEt2]2Journal of the American Chemical Society, 1994
- Experimental and theoretical studies of alkaline-earth metal coordination: x-ray crystal structures of calcium, strontium, and barium carbazoles and ab initio model calculationsJournal of the American Chemical Society, 1992
- The equilibrium structures of monomeric Group 2 and lanthanide(II) metallocenes MCp2 (M = calcium, strontium, barium, samarium, europium, ytterbium) studied by ab initio calculationsJournal of the American Chemical Society, 1992
- Do low-coordinated Group 1-3 cations Mn+Lm (Mn+ = potassium, rubidium cesium, calcium, strontium, barium, scandium, yttrium, lanthanum; L = ammonia, water, hydrogen fluoride; m = 1-3) with a formal noble-gas electron configuration favor regular or abnormal shapes?The Journal of Physical Chemistry, 1992
- The ions MCp2+ (M = scandium, lanthanum): significantly bent sandwich speciesOrganometallics, 1992
- A theoretical study of the positive and dipositive ions of M(NH3)n and M(H2O)n for M=Mg, Ca, or SrThe Journal of Chemical Physics, 1992
- The structural variations of monomeric alkaline earth MX2 compounds (M = calcium, strontium, barium; X = Li, BeH, BH2, CH3, NH2, OH, F). An ab initio pseudopotential studyJournal of the American Chemical Society, 1992
- The question of bending of the alkaline earth dihalides MX2 (M = beryllium, magnesium, calcium, strontium, barium; X = fluorine, chlorine, bromine, iodine). An ab initio pseudopotential studyJournal of the American Chemical Society, 1991
- Pseudopotential approaches to Ca, Sr, and Ba hydrides. Why are some alkaline earth MX2 compounds bent?The Journal of Chemical Physics, 1991
- Ground-state geometries and inversion barriers for simple complexes of early transition metalsInorganic Chemistry, 1989