The First Direct Synthesis of Corroles from Pyrrole
- 17 May 1999
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 38 (10) , 1427-1429
- https://doi.org/10.1002/(sici)1521-3773(19990517)38:10<1427::aid-anie1427>3.0.co;2-1
Abstract
The solvent-free, catalyst-free condensation of pyrrole and aldehydes provides an extremely facile synthetic pathway to novel corroles [Eq. (1); Ar=C6F5, 2,6-F2C6H3, 2,6-Cl2C6H3]. The product containing pentafluorophenyl groups is an excellent precursor of other derivatives, including an ionic, water-soluble corrole.This publication has 0 references indexed in Scilit: