2,3-Sigmatropic rearrangement of nucleophilic carbenes. A new approach to stereospecific synthesis of carbon–carbon bonds
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 354-355
- https://doi.org/10.1039/c39720000354
Abstract
S-Methyl-S-(3,3-dimethylallyl)carbene, generated by Bamford–Stevens reaction of the corresponding toluene-p-sulphonylhydrazone, undergoes a 2,3-sigmatropic rearrangement to a dithiocarboxylic acid ester, thereby providing a new carbon–carbon bond synthesis.Keywords
This publication has 0 references indexed in Scilit: