One-Pot Synthesis of Selenothioic Acid S-Alkyl Esters by the Reaction of Lithium Alkyneselenolates with Thiols
- 1 September 1993
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 22 (9) , 1469-1472
- https://doi.org/10.1246/cl.1993.1469
Abstract
The reaction of lithium alkyneselenolates generated from lithium alkynides and selenium powder with a variety of thiols afforded selenothioic acid S-alkyl esters in moderate to high yields. The product yields were highly dependent on the substituents of the starting acetylenes. The formation of unstable S-aryl ester was confirmed by the enolization followed by alkylation.This publication has 9 references indexed in Scilit:
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