The Infra‐red Spectra of Complexes with Planar Dithio Oxamides. Part II: The Pd(LH2) 2X2 Complexes
- 1 January 1982
- journal article
- research article
- Published by Wiley in Bulletin des Sociétés Chimiques Belges
- Vol. 91 (3) , 175-188
- https://doi.org/10.1002/bscb.19820910302
Abstract
Pd(II) gives square planar complexes Pd(LH2) 2X2 in acid media. X = Cl, Br, I; LH2 = Dithio oxamide (DTO), N methyldithio oxamide (RDTO) and NN′ dimethyldithio oxamide (RRDTO).These ligands act as bidentate ligands with S,S coordination. The hydrogen bonding ability is found to increase on passing from DTO to RRDTO and from Iodide to Chloride.Keywords
This publication has 9 references indexed in Scilit:
- The Infra-red Spectra of Complexes with Planar-dithio-Oxamides Part I: The Neutral PdL2 ComplexesBulletin des Sociétés Chimiques Belges, 1982
- Gold(I) complexes of thioamidesTransition Metal Chemistry, 1980
- The secondary thioamide function—I. The vibrational analysis of NN′ dimethyl-dithiooxamideSpectrochimica Acta Part A: Molecular Spectroscopy, 1979
- Palladium(II) complexes with primary thioamidesTransition Metal Chemistry, 1978
- Preparation, infrared, Raman and N.M.R. spectra of N,N′‐Diethylthiourea complexes with zinc(II), cadmium(II) and mercury(II) halidesZeitschrift für anorganische und allgemeine Chemie, 1976
- Chemical shifts and protonation shifts in carbon-13 nuclear magnetic resonance studies of aqueous aminesAnalytical Chemistry, 1975
- Palladium(II) complexes with dithiooxamide, N,N′-dimethyl- and N,N′-dicyclohexyl-dithiooxamideJournal of Inorganic and Nuclear Chemistry, 1973
- Hydrogen bonding in oxamides and thio-oxamidesSpectrochimica Acta Part A: Molecular Spectroscopy, 1972
- Hydrogen bonding intramolecular interactions in Co(II) complexes with thioureas and halogensJournal of Inorganic and Nuclear Chemistry, 1970