PeSeNPhth-TMSOTf as a Promotor of Thioglycoside
- 1 January 1994
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1994 (07) , 535-536
- https://doi.org/10.1055/s-1994-22919
Abstract
A new method to activate thioglycosides is described. The combined use of PhSeNPhth and TMSOTf was demonstrated to be a powerful promoter of thioglycoside. The reaction proceeds rapidly even at low temperature to give O-glycoside in a high yield. The effects of solvents and reaction temperature were also investigated.Keywords
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