Oxidative isomerisation as a probe of mixed valency in cyanide-bridged dimanganese carbonyl phosphine complexes
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1806-1808
- https://doi.org/10.1039/c39870001806
Abstract
The isomeric trans,trans- and cis,trans-[Mn2]2+-containing monocations (3+) and (4+) are oxidised to the trapped valence [Mn2]3+ dications (32+) and (42+); the oxidative isomerisation of (5+) to (32+) results from intramolecular electron transfer within (52+)Keywords
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