Abstract
Bis-alkoxy-disulfanes, ROSSOR, react with SCI, at 0 °C to give ROSSCl which yield the corresponding nonasulfanes, RO—S9—OR, on reaction with titanocene pentasulfide, (C5H5)2TiS5. Raman, mass, and NMR spectra of ROSSCl and (RO)2S9 (R = isopropyl) are reported.

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