A highly efficient titanium-based olefin polymerisation catalyst with a monoanionic iminoimidazolidide π-donor ancillary ligandElectronic supplementary information (ESI) available: experimental, spectroscopic and polymerisation details. See http://www.rsc.org/suppdata/cc/b1/b111343g/ Netherlands Institute for Catalysis Research (NIOK) publication no. RUG 01-4-05.
- 25 February 2002
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 6,p. 608-609
- https://doi.org/10.1039/b111343g
Abstract
The titanium complex Cp[1,3-(2′,6′-Me2C6H3)2(CH2N)2CN]Ti(CH2Ph)2, with a monoanionic η1-iminoimidazolidide ancillary ligand, is shown to be a highly efficient catalyst for olefin polymerisation when activated with the Lewis acid B(C6F5)3.Keywords
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