Mesoporous Spherical Aggregates of Anatase Nanocrystals with Wormhole-like Framework Structures: Their Chemical Fabrication, Characterization, and Photocatalytic Performance
- 20 November 2004
- journal article
- research article
- Published by American Chemical Society (ACS) in Langmuir
- Vol. 20 (26) , 11738-11747
- https://doi.org/10.1021/la0477892
Abstract
A facile and efficient approach for the fabrication of mesoporous spherical aggregates of anatase nanocrystals is reported in this paper. Cetyltrimethylammonium bromide was used as the structure-directing agent, and the interaction between cyclohexane microdroplets and the cetyltrimethylammonium bromide self-assemblies led to the assembly of 4−5-nm-sized anatase nanocrystals into spherical aggregates with mesoporous structures. The as-prepared anatase powders exhibited high photocatalytic activity and could be effectively used as the catalyst for the room-temperature photodegradation of a variety of organic dye pollutants in aqueous media including methyl orange, bromopyrogallol red, and methylene blue.Keywords
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