AuCl-Catalyzed Synthesis of Benzyl-Protected Substituted Phenols: A Formal [3+3] Approach
- 1 October 2007
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 9 (22) , 4627-4630
- https://doi.org/10.1021/ol7021356
Abstract
A AuCl-catalyzed synthesis of highly substituted, benzyl-protected phenols is developed. This reaction unites enal/enones and benzyl allenyl ether in a [3+3] fashion in two steps, allowing flexibility in phenol synthesis and excellent control of substitution at the benzene ring.Keywords
This publication has 6 references indexed in Scilit:
- Gold(I) Catalyzed Isomerization of 5-en-2-yn-1-yl Acetates: An Efficient Access to Acetoxy Bicyclo[3.1.0]hexenes and 2-Cycloalken-1-onesJournal of the American Chemical Society, 2006
- Phosphine Gold(I) Bis-(trifluoromethanesulfonyl)imidate Complexes as New Highly Efficient and Air-Stable Catalysts for the Cycloisomerization of EnynesOrganic Letters, 2005
- Formation of 1,4‐Diketones by Aerobic Oxidative C-C Coupling of Styrene with 1,3‐Dicarbonyl CompoundsAngewandte Chemie International Edition in English, 2004
- Mesoionic pyridazine ribonucleosides. A novel biologically active nucleoside metaboliteJournal of Medicinal Chemistry, 1984
- Diterpenes of the ferruginol type from Chamaecyparis pisiferaPhytochemistry, 1979
- CyclopropanolsAccounts of Chemical Research, 1968