Regiospecific formation of cyclopropylcarbinyl compounds in the reaction of but-3-enyliron complexes with electrophilic and radical reagents
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 622-623
- https://doi.org/10.1039/c39800000622
Abstract
3-Methylbut-3-enyldicarbonyl-η5-cyclopentadienyliron(II) reacts regiospecifically with free radicals (Cl3C·, Br3C·, ArSO2·) and with electrophiles (CF3CO2H) at the δ-carbon of the butenyl ligand, resulting in displacement of the metal and the formation of cyclopropylcarbinyl compounds in high yield.Keywords
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