Transition metal–carbon bonds. Part XXII. Pyrolysis of some methylplatinum(IV) complexes
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2969-2970
- https://doi.org/10.1039/j19690002969
Abstract
Some methylplatinum(IV) complexes of the type [PtXyMe4–yL2](X = halogen; y= 0–3; L = PMe2Ph or AsMe2Ph) have been pyrolysed and the gases evolved and the platinum(II) complexes formed have been identified. Acetyl complexes of the type [PtXMe2(COMe)L2] on pyrolysis give acetone and trans-[PtXMeL2] in quantitative yields.Keywords
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