Oxygen insertion into the metal–carbon bond of cyclopalladated 2-(alkylsulphinyl)azobenzenes by peracids. High yield regiospecific aromatic hydroxylation
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 468-470
- https://doi.org/10.1039/c39880000468
Abstract
The title reaction occurs by an associative mechanism involving heterolytic O–O cleavage; the sequence azobenzene →(1)→(2)→ azophenol leading to overall regiospecific aromatic hydroxylation has been realised.Keywords
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