Application of the Dewar–Zimmerman rules to the reactions between radical cations and nucleophiles
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 826-827
- https://doi.org/10.1039/c39750000826
Abstract
The reaction between a 4n+1 aromatic radical cation and a nucleophile, the interacting orbital of which must be used suprafacially in the transition state, should be ‘forbidden’ by the Dewar–Zimmerman rules.Keywords
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