Stereochemical effects on the spin-state transition shown by salts of [FeL2]2+ [L = 2,6-di(pyrazol-1-yl)pyridine]
- 28 January 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 4,p. 548-554
- https://doi.org/10.1039/b108468m
Abstract
The syntheses of [Fe(L1H)2]X2 (L1H = 2,6-di(pyrazol-1-yl)pyridine [L1H]; X− = BF4 −, PF6 −) are described. Solvent-free [Fe(L1H)2][BF4]2 shows an approximately D2d-symmetric metal centre in the crystal, and undergoes an unusual abrupt spin-state transition centered at 261 K in the solid, or at 248 K in acetone solution. A solvated phase [Fe(L1H)2][BF4]2·2.9CH3NO2·0.25H2O can be grown at 240 K, which undergoes an irreversible spin-state transition between 260 and 265 K. In contrast, solid [Fe(L1H)2][PF6]2 adopts an unusual C2-symmetric coordination geometry, reflecting a ca. 28° twist of one L1H ligand with respect to each other. This salt is high-spin in the range 10–330 K. DFT calculations have rationalised this unusual structure as a Jahn–Teller distortion of the 5E ground state of the six-coordinate Fe(II) ion. This distortion is favoured by the restricted bite-angle of the L1H ligands.Keywords
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