A new example of a palladium-assisted aryl rearrangement. Synthesis and reactivity of (2,3,4-trimethoxy-6-X-phenyl)Pd [X = CHO, CH:N(n-C10H21), CH:NC6H4(NH2)-2, C(O)Me] and (3,4,5-trimethoxy-2-X-phenyl)Pd [X = CHO, CH:NC6H4(NH2)-2] complexes. Crystal and molecular structure of [Pd(.kappa.3-C6H[CH:NC6H4(NH2)-2]-6-(OMe)3-2,3,4)(PPh3)]CF3SO3, [Pd(.kappa.3-C6H[CH:NC6H4(NH2)-2]-2-(OMe)3-3,4,5)(PPh3)]CF3SO3, and [Pd(.kappa.2-C6H[C(O)Me]-6-(OMe)3-2,3,4)(2,9-dimethyl-1,10-phenanthroline)]CF3SO3
- 1 October 1993
- journal article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 12 (10) , 4151-4160
- https://doi.org/10.1021/om00034a059
Abstract
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