C60 end-capped polystyrene stars
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 13,p. 1565-1566
- https://doi.org/10.1039/cc9960001565
Abstract
A hexaarm hexachloropolystyrene star polymer 1 ( n= 18 000 g mol–1) is functionalized by reaction with Me3SiN3 to give the hexaazido star polymer 2; reduction of 2 by PPh3/H2O leads to the hexaamine star polymer 3, and reaction of 2 with a two-fold excess of C60 gives the hexafullerence star polymer 4, characterized by size-exclusion chromatography, NMR, thermal-gravimetry analysis and CV.Keywords
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