C-Nucleosides and related compounds. XIV. The synthesis of a nitrogen analogue of showdomycin
- 15 August 1977
- journal article
- research article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 55 (16) , 2998-3006
- https://doi.org/10.1139/v77-417
Abstract
Starting from teloidinone 5a, 2-(2′α,3′α-dihydroxy-4′β-hydroxymethyl-N-carbomethoxypyrrolidin-1β-yl)maleimide 1b, a showdomycin analogue in which the ribofuranosyl ring oxygen is replaced by an N-carbomethoxy group, has been synthesized in 7% overall yield.Keywords
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