Distorted Wave Calculation of Vibrational Excitation and Transfer in H2 and D2
- 15 May 1972
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 56 (10) , 5071-5074
- https://doi.org/10.1063/1.1676989
Abstract
A numerical three‐dimensional distorted wave calculation has been made for V‐T and V‐V vibrational excitation cross sections in H2, D2, and their mixtures, for energies within 1.5 eV of threshold. The corresponding relaxation times have been calculated for temperatures between 300 and 1000°K and the results compared with shock‐tube and stimulated Raman emission data.Keywords
This publication has 8 references indexed in Scilit:
- Classical Isotope Effect in Vibrational Relaxation: The Relaxation of H2 and D2The Journal of Chemical Physics, 1968
- Collision of an Atom and a Diatomic. The Distorted Wave ExpansionThe Journal of Chemical Physics, 1968
- Exact Quantum-Mechanical Calculation of a Collinear Collision of a Particle with a Harmonic OscillatorThe Journal of Chemical Physics, 1966
- Stimulated Raman Scattering in Hydrogen: A Measurement of the Vibrational LifetimePhysical Review Letters, 1966
- Vibrational Relaxation of HydrogenThe Journal of Chemical Physics, 1966
- Excitation of Molecular Vibration on CollisionThe Journal of Chemical Physics, 1958
- Method of Calculating Cross Sections for Molecular CollisionsThe Journal of Chemical Physics, 1955
- Energy exchange between inert gas atoms and a solid surfaceProceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character, 1932