Regio- and stereo-specific electroreduction of cationic acylcyclopentadienylareneiron complexes
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 512-513
- https://doi.org/10.1039/c39760000512
Abstract
Activation of a carbonyl group in cationic organometallic substrates such as the acylcyclopentadienylareneiron complexes(I), (V), and (VII) renders its electrochemical reduction easy and stereospecific, providing a route to the primary and secondary cationic alcohols (II) and (VI) or to the dinuclear dicationic pinacols (III).Keywords
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