Generation of metal–carbon and metal–nitrogen clusters with a laser induced plasma technique

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Abstract
During the course of investigating dehydrogenation reactions induced by transition metals, we find that using a carrier gas containing hydrocarbons and ammonia instead of pure helium, in conjunction with a laser vaporization device, enables the facile production of metal–carbon and metal–nitrogen clusters in both the neutral and ionic forms. With only a change in the nature of the carrier gas, a variety of new classes of clusters can be produced.