Resonant photoemission studies of the heavy-fermion superconductors CeCu2Si2, UBe13, and UPt3

Abstract
Valence-band photoemission studies, using synchrotron light and employing Fano resonances to enhance f-derived features, were made of the three known heavy-fermion superconductors: CeCu2 Si2, UBe13, and UPt3. The results for CeCu2 Si2 and UBe13 contrast markedly with those reported earlier, reflecting closer control of surface contamination in the present study. We infer from the present study and other considerations that in all three systems there is significant hybridization between the f electrons and the nearest-neighbor ligands, which may be essential to the phenomenon of heavy-fermion superconductivity.