Solution and crystal structure of the dihydrogen complex [Ru(H2)(H)(PMe2Ph)4]PF6, an active alkyne hydrogenation catalyst
- 2 April 1998
- journal article
- Published by Elsevier in Inorganica Chimica Acta
- Vol. 270 (1-2) , 238-246
- https://doi.org/10.1016/s0020-1693(97)05849-0
Abstract
No abstract availableKeywords
This publication has 31 references indexed in Scilit:
- 1995 Alcan Award Lecture New intermediates in the homolytic and heterolytic splitting of dihydrogenCanadian Journal of Chemistry, 1996
- C−C Bond Formation between Vinylidene and Alkynyl Ligands at Ruthenium(II) Leading to either Enynyl or Dienynyl ComplexesOrganometallics, 1996
- Asymmetric Hydrogenation.Acta Chemica Scandinavica, 1996
- Dihydrogen with Frequency of Motion Near the1H Larmor Frequency. Solid-State Structures and Solution NMR Spectroscopy of Osmium Complexestrans-[Os(H··H)X(PPh2CH2CH2PPh2)2]+(X = Cl, Br)Journal of the American Chemical Society, 1996
- Use of the new ligand P(CH2CH2PCy2)3 in the synthesis of dihydrogen complexes of iron(II) and ruthenium(II)Organometallics, 1993
- Preparation and spectroscopic properties of the .eta.2-dihydrogen complexes [MH(.eta.2-H2)PR2CH2CH2PR2)2] + (M = iron, ruthenium; R = Ph, Et) and trends in properties down the iron group triadJournal of the American Chemical Society, 1991
- NMR properties of the complexes trans-[M(.eta.2-H2)(H)(PEt2CH2CH2PEt2)2]+ (M = Fe, Ru, Os). Intramolecular exchange of atoms between .eta.2-dihydrogen and hydride ligandsJournal of the American Chemical Society, 1987
- Solution structure of five-coordinate complexes of ruthenium(II): evidence for a square-pyramidal geometry for the cations [RuXL4]+ (X = H, C2Ph; L = PMe2Ph)Inorganic Chemistry, 1985
- Cationic ruthenium(II) systems. Part 1. The preparation and reactivity of diene(hydrazine)ruthenium(II) cations, and the formation of aminobonded hydrazone complexesJ. Chem. Soc., Dalton Trans., 1977
- Cationic ruthenium systems. Part 2. Synthesis, characterization, and X-ray structure of hydridopentakis(dimethylphenylphosphine)-ruthenium(II) hexafluorophosphate: a discussion of the effects of steric strains on the reactivity of the complexJ. Chem. Soc., Dalton Trans., 1977