Photoracemization at a chiral pyramidal nitrogen centre
- 1 January 1976
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 162-163
- https://doi.org/10.1039/c39760000162
Abstract
The absorption of u.v. light by chiral oxaziridines having a stable pyramidal nitrogen configuration results in photoracemization via a mechanism involving C–O bond cleavage and a nitrone intermediate.Keywords
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