The dissociative interchange substitution of the pentacyanocobaltate(III) series of complexes, [Co(CN)5X]n–, n= 2 or 3
- 1 January 1983
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 833-834
- https://doi.org/10.1039/c39830000833
Abstract
The efficiency of nucleophiles, (N3 –, NCS– and Me2SO) in combining with the intermediate [Co(CN)5]2–depends on the ion from which the intermediate is formed, [Co(CN)5(OH2)]2–, [Co(CN)5Cl]3–, or [Co(CN)5(N3H)]2–, thereby suggesting that the substitution of these ions takes place by dissociative interchange, Id.Keywords
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