Magnetic and spectroscopic study of some binuclear and trinuclear cobalt(II) carboxylate complexes
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 10,p. 2211-2214
- https://doi.org/10.1039/dt9860002211
Abstract
Binuclear [Co2(RCO2)4L2] and trinuclear [Co3(RCO2)6L2] cobalt(II) carboxylate complexes have been prepared (R = unsaturated alkyl, L = sterically hindered amine). The roles of electronic and steric effects on the formation of oligonuclear cobalt(II) carboxylates are discussed. The temperature dependence of their antiferromagnetism shows variations as R and L are altered.Keywords
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