Reaction of 4-Nitrophthalonitrile with Carbonate, Nitrite, and Fluoride
- 1 November 1989
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 19 (18) , 3231-3239
- https://doi.org/10.1080/00397918908052723
Abstract
In DMSO and DMF at elevated temperatures, KF, KNO2, NaNO2, K2CO3, and Na2CO3 react with 4-nitrophthalonitrile to form 4,4′-oxybis-(phthalonitrile) and, mostly, 4-hydroxyphthalonitrile. Formation ratios depend on reaction conditions. Intermediates are discussed.Keywords
This publication has 6 references indexed in Scilit:
- Metallophthalocyanine dimers incorporating five-atom covalent bridgesCanadian Journal of Chemistry, 1985
- Syntheses and characterization of heteroatom-bridged metal-free phthalocyanine network polymers and model compoundsMacromolecules, 1984
- Metal‐chelating 1,3‐bis(2′‐pyridylimino)isoindolinesJournal of Heterocyclic Chemistry, 1981
- Reactions of fluoride and nitrite ions with 4-nitrophthalimidesThe Journal of Organic Chemistry, 1977
- Spectroscopic evidence for electron transfer preceding or accompanying nucleophilic aromatic displacement reactions on nitrophthalic systems with 4-methylphenoxide ionJournal of the American Chemical Society, 1977
- Phthalonitrile ResinsPublished by American Chemical Society (ACS) ,1975